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The state of Pennsylvania is ranked 33rd in the country for a total land area of 46,055 sq miles. The population of Pennsylvania is ranked 6th in the country with 12,784,227 (2016 est) residents. The capital of Pennsylvania is Harrisburg and the Largest city is Philadelphia. Pennsylvania's nicknames are the Keystone State and Quaker State. On December 12th, 1787, Pennsylvania was the 2nd state admitted to the Union.